Serveur d'exploration sur le cobalt au Maghreb

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New ordered and distorted perovskites: the mixed platinates Ln2MptO6 (Ln = La, Pr, Nd, Sm, Eu, Gd; M = Mg, Co, Ni, Zn)

Identifieur interne : 000195 ( Maroc/Analysis ); précédent : 000194; suivant : 000196

New ordered and distorted perovskites: the mixed platinates Ln2MptO6 (Ln = La, Pr, Nd, Sm, Eu, Gd; M = Mg, Co, Ni, Zn)

Auteurs : K. Ouchetto [France] ; F. Archaimbault [France] ; J. Choisnet [France] ; M. Et-Tabirou [Maroc]

Source :

RBID : ISTEX:132142C5EA4B349270E93ED0C32E9C98ACA8AC30

English descriptors

Abstract

Abstract: A new series of perovskite-like mixed platinates Ln2MPtO6 (Ln = La, Pr, Nd, Sm, Eu, Gd; M = Mg, Co, Ni, Zn) has been obtained from solid state synthesis. In spite of the difficulty of achieving the formation of pure phases, the crystallographic characterization allows us to point to a GdFeO3 type model with a full 1/1 ordering of the M2+ and Pt4+ cations on the octahedral sites of a distorted ‘ReO3’ network. The results of an X-ray powder Rietveld analysis give evidence of strong crystallochemical similarities with the corresponding iridates and ruthenates. Among the different M2+ cations herein considered, the particular case of Co2+ is emphasized as bringing another proof of the occurrence of its actual size, smaller than modelled.

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DOI: 10.1016/S0254-0584(97)80279-9


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ISTEX:132142C5EA4B349270E93ED0C32E9C98ACA8AC30

Le document en format XML

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